METHOXYPROPYLAMINE

 Synonyms: METHOXYPROPYLAMINE, MOPA , gamma.-Methoxypropaneamine,1-Propanamine,3-methoxy-,3-methoxy-1-propanamin,3-Methoxy-1-propylamine,3-Methoxy-n-propylamine,3-methoxy-propylamin,3-Methyoxypropylamine, propanolaminemethylether
 CAS# : 5332-73-0
 Formula : C4H11NO

Hazard Information:

TDG   Hazard class: 8 Packing group: I ID number: UN 2734 Hazard label: 8, 3 Proper shipping name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (contains 3- METHOXYPROPYLAMINE)
IATA/ICAO   Hazard class: 8 Packing group: I ID number: UN 2734 Hazard label: 8, 3 Proper shipping name: AMINES, LIQUID, CORROSIVE,
 HMIS Code  3-3-0
 WHMIS Classification B2, D2B, E
 US, TSCA    Listed
 Canada, DSL           Listed
 Australia, AICS Listed
 Europe, EINECS/ELINCS Listed
 Japan, METI Listed

Specifications:

Property                                Specifications Test Method
Appearance  Clear and substantially free of foreign matter ST-30.1  
Color, Pt-Co  25 max ST-30.12  
3-Methoxypropylamine, wt. % 99 min. ST-5.5  
Typical Physical Properties
Boiling point, °C (°F)            116 (240)  
Flash point, TCC, °C (°F) 27 (81)    
Freezing point, °C (°F) – 76 (-104)  
Ionization constant, Kb, 25°C 1.3 x 10-4  
Ionization constant, pKb 3.9  
Molecular weight 89.14  
pH       11  
Refractive index, n20          1.4180  
Specific Gravity 0.87  
Surface tension, dynes/cm2, 25°C 27.64  
Vapor pressure, mm Hg, 20°C (68°F) 6  
Viscosity, cSt, 37.8°C (100°F) 0.8  
Water solubility > 10  

Packaging: 

Tank cars, Tank wagons, and 55-gallon drums

Applications:

  • Amine soaps prepared from methoxypropylamine and fatty acids are useful for making dispersion and emulsions of certain synthetic and natural resins and waxes which are useful in floor finishes, textile finishes, water-based paints and in similar areas of application.
  • Useful for preparing water-insensitive waxes. It volatilizes with water and leaves behind an insoluble wax film. Further, in dilute solutions does not have an objectionable odor. The material has been compared with morpholine in such applications and may, in fact, function as a substitute for morpholine in some instances.
  • Used in insecticide emulsions, dye solvents, textile assistants, and in general, applications in which mild bases of moderate volatility are desired.
  • It has been used in the production of dyes to modify polybutadiene-based isocyanates and in the manufacture of polyamide resins.
  • The treatment of aluminum and aluminum alloy surfaces with dilute solutions of methoxypropylamine is reported to improve the adherence of various coatings which may be subsequently applied.
  • The  reaction  of  methoxypropylamine  with  bis(2-carbamoylphenyl)  disulfides  is  reported  to  give  products  useful  in controlling mildew fungi in latex and alkyd paints.
  • Similar products are obtained by reacting methoxypropylamine with quinones, carbamates, benzothiazole and other substrates.
  • Compounds effective against silicosis have been reported from the reaction of methoxypropylamine with styrene-maleic anhydride copolymer and a diamine.
  • Aphenol-free paint remover has been prepared from methoxypropylamine and sodium hydroxide. Plant growth regulators were prepared from this product.
  • A fluorescent brightener for cellulosic textiles was prepared from methoxypropylamine. It is reported to have improved low-temperature effectiveness and did not discolor washing powders.
  • Water soluble polyelectrolytes for use as flocculating agents have been prepared by reacting methoxypropylamine with acrylonitrile polymers.
  • Used to inhibit corrosion in steam condensate systems. The addition of the amine in the parts per million level is effective in reducing corrosion caused by the presence of carbon dioxide in the water.
  • An additive to prevent corrosion of oil refining  equipment. The presence of acidic materials in the incoming crude causes corrosion at the points of initial water condensation.

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